Continuous Hydrogenation of Aqueous Furfural Using a Metal-Supported Activated Carbon Monolith

Continuous hydrogenation of aqueous furfural (4.5%) was studied using a monolith form (ACM) of an activated carbon Pd catalyst (∼1.2% Pd). A sequential reaction pathway was observed, with ACM achieving high selectivity and space time yields (STYs) for furfuryl alcohol (∼25%, 60-70 g/L-cat/h, 7-15 1/h liquid hourly space velocity, LHSV), 2-methylfuran (∼25%, 45-50 g/L-cat/h, 7-15 1/h LHSV), and tetrahydrofurfuryl alcohol (∼20-60%, 10-50 g/L-cat/h, <7 1/h LHSV). ACM showed a low loss of activity and metal leaching over the course of the reactions and was not limited by H₂ external mass transfer resistance. Acetic acid (1%) did not significantly affect furfural conversion and product yields using ACM, suggesting Pd/ACM's potential for conversion of crude furfural. Limited metal leaching combined with high metal dispersion and H₂ mass transfer rates in the composite carbon catalyst (ACM) provides possible advantages over granular and powdered forms in continuous processing.