Surface Modification of Fe₇ S₈ /C Anode via Ultrathin Amorphous TiO₂ Layer for Enhanced Sodium Storage Performance

Iron sulfides with high theoretical capacity and low cost have attracted extensive attention as anode materials for sodium ion batteries. However, the inferior electrical conductivity and devastating volume change and interface instability have largely hindered their practical electrochemical properties. Here, ultrathin amorphous TiO₂ layer is constructed on the surface of a metal-organic framework derived porous Fe₇ S₈ /C electrode via a facile atomic layer deposition strategy. By virtue of the porous structure and enhanced conductivity of the Fe₇ S₈ /C, the electroactive TiO₂ layer is expected to effectively improve the electrode interface stability and structure integrity of the electrode. As a result, the TiO₂ -modified Fe₇ S₈ /C anode exhibits significant performance improvement for sodium-ion batteries. The optimal TiO₂ -modified Fe₇ S₈ /C electrode delivers reversible capacity of 423.3 mA h g^-1 after 200 cycles with high capacity retention of 75.3% at 0.2 C. Meanwhile, the TiO₂ coating is conducive to construct favorable solid electrolyte interphase, leading to much enhanced initial Coulombic efficiency from 66.9% to 72.3%. The remarkable improvement suggests that the interphase modification holds great promise for high-performance metal sulfide-based anode materials for sodium-ion batteries.