A Nano-Rattle SnO₂@carbon Composite Anode Material for High-Energy Li-ion Batteries by Melt Diffusion Impregnation

The huge volume expansion in Sn-based alloy anode materials (up to 360%) leads to a dramatic mechanical stress and breaking of particles, resulting in the loss of conductivity and thereby capacity fading. To overcome this issue, SnO₂@C nano-rattle composites based on <10 nm SnO₂ nanoparticles in and on porous amorphous carbon spheres were synthesized using a silica template and tin melting diffusion method. Such SnO₂@C nano-rattle composite electrodes provided two electrochemical processes: a partially reversible process of the SnO₂ reduction to metallic Sn at 0.8 V vs. Li⁺/Li and a reversible process of alloying/dealloying of Li_xSn_y at 0.5 V vs. Li⁺/Li. Good performance could be achieved by controlling the particle sizes of SnO₂ and carbon, the pore size of carbon, and the distribution of SnO₂ nanoparticles on the carbon shells. Finally, the areal capacity of SnO₂@C prepared by the melt diffusion process was increased due to the higher loading of SnO₂ nanoparticles into the hollow carbon spheres, as compared with Sn impregnation by a reducing agent.