Recent progress on the enhancement of photocatalytic properties of BiPO₄ using π-conjugated materials

Semiconductor photocatalysis is regarded as most privileged solution for energy conversion and environmental application. Recently, photocatalysis methods using bismuth-based photocatalysts, such as BiPO₄, have been extensively investigated owing to their superior efficacy regarding organic pollutant degradation and their further mineralization into CO₂ and H₂O. It is well known that BiPO₄ monoclinic phase exhibited better photocatalytic performance compared to Degussa (Evonik) P25 TiO₂ in term of ultraviolet light driven organic pollutants degradation. However, its wide band gap, poor adsorptive performance and large size make BiPO₄ less active under visible light irradiation. However, extensive research works have been conducted in the past with the aim of improving visible light driven BiPO₄ activity by constructing a series of heterostructures, mainly coupled with π-conjugated architecture (e.g., conductive polymer, dye sensitization and carbonaceous materials). However, a critical review of modified BiPO₄ systems using π-conjugated materials has not been published to date. Therefore, this current review article was designed with the aim of presenting a brief current state-of-the-art towards synthesis methods of BiPO₄ in the first section, with an especial focuses onto its crystal-microstructure, optical and photocatalytic properties. Moreover, the most relevant strategies that have been employed to improve its photocatalytic activities are then addressed as the main part of this review. Finally, the last section presents ongoing challenges and perspectives for modified BiPO₄ systems using π-conjugated materials.