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Atomically Thin Oxyhalide Solar-Blind Photodetectors.

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High-responsivity solar-blind photodetectors were developed using 2D bismuth oxychloride (BiOCl) flakes. These devices show promise for solar-blind ultraviolet detection, especially at elevated temperatures.

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Area of Science:

  • Materials Science
  • Optoelectronics
  • Nanotechnology

Background:

  • Two-dimensional (2D) wide-bandgap semiconductors offer potential for solar-blind ultraviolet (SBUV) photodetectors.
  • Low responsivity in current 2D SBUV photodetectors hinders practical applications.

Purpose of the Study:

  • To achieve high-responsivity SBUV photodetectors using 2D bismuth oxychloride (BiOCl) flakes.
  • To investigate the effect of ambient temperature on the performance of BiOCl-based photodetectors.

Main Methods:

  • Fabrication of SBUV photodetectors using 2D BiOCl flakes.
  • Characterization of photodetector performance under 250 nm illumination.
  • In situ transmission electron microscopy to observe material changes at elevated temperatures.

Main Results:

  • The 2D BiOCl photodetectors achieved a responsivity of 35.7 A W⁻¹ and detectivity of 2.2 × 10¹⁰ Jones at room temperature.
  • Responsivity significantly increased to 2060 A W⁻¹ at 450 K.
  • Defective BiOCl grains were observed at higher temperatures, potentially explaining the enhanced performance.

Conclusions:

  • 2D BiOCl is a promising material for high-responsivity SBUV photodetectors.
  • Elevated temperatures can dramatically enhance the performance of BiOCl-based photodetectors.
  • Defect engineering in BiOCl warrants further investigation for SBUV applications.