First observation of tropospheric nitrogen dioxide from the Environmental Trace Gases Monitoring Instrument onboard...

The Environmental Trace Gases Monitoring Instrument (EMI) is the first Chinese satellite-borne UV-Vis spectrometer aiming to measure the distribution of atmospheric trace gases on a global scale. The EMI instrument onboard the GaoFen-5 satellite was launched on 9 May 2018. In this paper, we present the tropospheric nitrogen dioxide (NO₂) vertical column density (VCD) retrieval algorithm dedicated to EMI measurement. We report the first successful retrieval of tropospheric NO₂ VCD from the EMI instrument. Our retrieval improved the original EMI NO₂ prototype algorithm by modifying the settings of the spectral fit and air mass factor calculations to account for the on-orbit instrumental performance changes. The retrieved EMI NO₂ VCDs generally show good spatiotemporal agreement with the satellite-borne Ozone Monitoring Instrument and TROPOspheric Monitoring Instrument (correlation coefficient R of ~0.9, bias < 50%). A comparison with ground-based MAX-DOAS (Multi-Axis Differential Optical Absorption Spectroscopy) observations also shows good correlation with an R of 0.82. The results indicate that the EMI NO₂ retrieval algorithm derives reliable and precise results, and this algorithm can feasibly produce stable operational products that can contribute to global air pollution monitoring.