Comparison of furfural and biogas production using pentoses as platform

Coffee cut-stems (CCS), a biomass with high lignocellulosic content, is a coffee crop waste after bean harvesting. The main application of this material is as fuelwood for farmers, disregarding their carbohydrate content for biotechnological processes. In these terms, this work aims to compare three process scenarios for the experimental valorization of C5 fraction from CCS to produce biogas and furfural with and without the ethanol production from remaining C6 fraction under biorefinery concept. Therefore, an experimental stage was performed to obtain these products, based on a previous diluted acid pretreatment. The hydrolysate fraction was used to produce furfural and biogas, achieving yields of 0.34 g of furfural/g xylose and 81.1 mL of CH₄ per gram of volatile solids. Concerning the solid fraction after acid pretreatment, it was used to produce ethanol with a previous enzymatic hydrolysis. After fermentation, 0.47 g of ethanol/g of glucose (92% of the theoretical yield) was obtained. These experimental results were fed to simulation models in order to compare three scenarios in technical, economic and environmental terms. As the main results, from technical point of view, the biogas production presents the lowest energy requirements. From the economic perspective, the furfural production presents a prefeasibility at the base scale of processing (e.g., 12.5 ton h^-1). Meanwhile, the biogas scenario needs a processing capacity >22.5 ton h^-1 to achieve the economic prefeasibility. In the biorefinery case, the positive economic performance is found at processing scales above 83 ton h^-1. This work concludes that the C5 sugars platform is identified as a potential alternative for the generation of furfural and biogas, however, in this case a multiproduct biorefinery system is not always the best option to valorize biomass given the very high scale required and the economic indicators.