Application and Properties of Microporous Carbons Activated by ZnCl₂: Adsorption Behavior and Activation Mechanism

Herein, polypyrrole-based porous carbon (PPC) was prepared by ZnCl₂ activation for toluene adsorption from paraffin liquid. The structure properties were adjusted by a dosage of activating agents and carbonization temperature. The result with a 3:1 mass ratio of ZnCl₂/PPy at 600 °C showed the highest micropore area and percentage of micropore volume of 1105 m²/g and 86.26%, respectively. In addition, the PPC surface was rich in functional groups and obtained a high N-doped content from 7.00 to 8.82%. The toluene adsorption behavior onto the PPC was comprehensively investigated including isotherms, kinetics, and thermodynamics. The adsorption isotherm accorded with the Freundlich model well, and the kinetic model was fitted more closely to the pseudo-second-order chemisorption. The thermodynamic research uncovered that the adsorption was spontaneous and an endothermic process in essence. The ZnCl₂ activation mechanism is discussed based on TG/TGA curves and pore structure analysis at last. The devised way of synthesized microporous carbon is green and simple, which is suited to mass production for the adsorption of toluene from paraffin liquid and reducing environmental pollution.