Efficient charge generation at low energy losses in organic solar cells: a key issues review

Light absorption generates strongly bound excitons in organic solar cells (OSCs). To obtain efficient charge generation, a large driving force is required, which causes a large energy loss (E _loss) and severely hinders the improvement in the power conversion efficiencies (PCEs) of OSCs. Recently, the development of non-fullerene OSCs has seen great success, and the resulting OSCs can yield highly efficient charge generation with a negligible driving force, which raises a fundamental question about how the excitons split into free charges. From a chemical structure perspective, the molecular electrostatic potential differences between donors and acceptors may play a critical role in facilitating charge separation. Although the E _loss caused by charge generation has been suppressed, charge recombination, particularly via non-radiative pathways, severely limits further improvements in the PCEs. In OSCs with negligible driving forces, the lowest excited state, a hybrid local exciton-charge transfer state, is believed to have a strong association with the non-radiative E _loss. This review discusses the efficient charge generation at low E _loss values in highly efficient OSCs and highlights the issues that should be tackled to further improve the PCEs to new levels (∼20%).