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Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism01:18

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Birch reduction uses solvated electrons as reducing agents. The reaction converts benzene to 1,4-cyclohexadiene. The reaction proceeds by the transfer of a single electron to the ring to form a benzene radical anion. This anion is highly basic—it abstracts a proton from the alcohol to form a cyclohexadienyl radical. Another single electron transfer gives the cyclohexadienyl anion. A proton transfer from the alcohol forms 1,4-cyclohexadiene. Since this reduction occurs via radical anion...
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Author Correction: Bismuthene for highly efficient carbon dioxide electroreduction reaction.

Fa Yang1,2, Ahmed O Elnabawy3, Roberto Schimmenti3

  • 1State Key Laboratory of Electroanalytical Chemistry, & Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, 130022, Changchun, P.R. China.

Nature Communications
|May 8, 2020
PubMed
Summary

An amendment to this scientific paper has been published. Please refer to the link at the top of the document for the updated version.

Area of Science:

  • Not specified in the abstract.

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