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The migration dynamics and the speciation of arsenic in the Hetao area, Inner Mongolia
1School of Environmental Science and Engineering, Shanghai Jiaotong University, 800 Dongchuan Rd., Shanghai, 200240, People's Republic of China. huizhang@sjtu.edu.cn.
Abstract:
Arsenic contamination of the groundwater in the Hetao area in Inner Mongolia, China, has been a serious problem since the 1980s. In this study, the behavioral mechanics of arsenic in soil in the Hetao area, in relation to arsenic concentrations in groundwater, were studied using elemental speciation analysis. It is for probing the possible mechanisms of correlation and interaction within water and soil of the area, which is little work on it not only in the Hetao area but also worldwide. Associated with our previous work on water in this area, soil samples were collected along transects through areas strongly affected by arsenic poisoning. Sequential extractions were used to determine the speciation in soil of arsenic and other elements (Cd, Cu, Mo, Pb, Sb, Sn, and Zn) which are with similar geochemical behaviors to arsenic in natural systems. The results show that the arsenic concentration in soil is correlated with arsenic concentration in groundwater. This implies that arsenic transformation as a main factor of the resident poisoning of the area could be related with groundwater and soil. These results suggest that arsenic poisoning in the Hetao area is related with water and soil. The tracers moving through water are retained in the shallow stratum including soil and persist in the water affected by the movement of arsenic through the shallow stratum and soil. Graphical abstract.
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