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States of Water01:23

States of Water

55.7K
Water exists in any one of the three classical states: solid (ice), liquid (water), and gas (steam or water vapor). The state of water depends on i) the intermolecular forces that draw molecules together and ii) the kinetic energy that leads to movements that pull them apart.
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
55.7K
Surface Tension of Fluid01:22

Surface Tension of Fluid

1.1K
Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies...
1.1K
Intermolecular Forces03:13

Intermolecular Forces

68.1K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
68.1K
Solubility Equilibria: Ionic Product of Water01:16

Solubility Equilibria: Ionic Product of Water

1.4K
Pure water is a weak electrolyte; only a small amount ionizes into hydrogen and hydroxide ions. At any given temperature, the concentration of undissociated water is almost constant, so the ionic product of water is the product of the hydrogen and hydroxide ion concentrations, denoted as Kw. The square root of Kw gives the individual ion concentrations.
The ionic product of water varies with temperature, and its value is 1.0 x 10−14 at standard experimental conditions. Per Le...
1.4K
Capillarity in Fluid01:19

Capillarity in Fluid

708
Capillarity describes the movement of liquid in small spaces without external forces acting on it. The capillarity is driven by surface tension and adhesive interactions between the liquid and surrounding solid surfaces. This effect is often seen in narrow tubes, porous materials, and fine particles.
Surface tension is crucial to capillarity. It results from cohesive forces between liquid molecules at the liquid-air boundary, forming a skin that resists external forces. When the capillary tube...
708
Cohesion01:07

Cohesion

57.9K
Cohesion is the attraction between molecules of the same type, such as water molecules. Water molecules have an overall neutral charge but are polar molecule. An oxygen atom in one water molecule has a partial negative charge that can bind to a hydrogen atom with a partial positive charge in a second water molecule, forming a hydrogen bond. Each water molecule can form up to four hydrogen bonds with other water molecules. Hydrogen bonds are responsible for water's cohesive nature.
On a...
57.9K

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Updated: Dec 22, 2025

Molecular Entanglement and Electrospinnability of Biopolymers
07:59

Molecular Entanglement and Electrospinnability of Biopolymers

Published on: September 3, 2014

15.0K

Water above the spinodal.

Michal Duška1

  • 1Institute of Thermomechanics of the CAS, v. v. i., Dolejškova 1402/5, Prague 182 00, Czech Republic and Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742, USA.

The Journal of Chemical Physics
|May 10, 2020
PubMed
Summary
This summary is machine-generated.

Researchers developed a new equation of state to locate the liquid-liquid critical point, refuting spinodal reentrance as an explanation for water anomalies. Findings support the liquid-liquid critical point as the primary cause.

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Last Updated: Dec 22, 2025

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Area of Science:

  • Thermodynamics
  • Physical Chemistry
  • Water Science

Background:

  • The liquid spinodal and liquid-liquid critical point are crucial for understanding water anomalies but have been difficult to locate experimentally.
  • Existing scenarios explaining water anomalies lack experimental validation and theoretical tools for localization.

Purpose of the Study:

  • To develop a novel equation of state capable of localizing the spinodal and liquid-liquid critical point.
  • To critically evaluate existing explanations for water anomalies, particularly those involving spinodal reentrance.

Main Methods:

  • Construction of a unique equation of state combining Speedy's expansion with a liquid-liquid critical point.
  • Independent depiction of the spinodal in the presence of the liquid-liquid critical point.
  • Analysis of hydrogen bond cooperativity's role in critical point positioning.

Main Results:

  • The proposed equation of state successfully depicts the spinodal and liquid-liquid critical point independently.
  • Demonstrated that spinodal reentrance is not a valid explanation for water anomalies.
  • Identified hydrogen bond cooperativity as essential for a non-zero temperature critical point.
  • Highlighted discrepancies between major experimental heat capacity datasets, identifying a more accurate one.

Conclusions:

  • The liquid-liquid critical point at positive pressure is the most plausible explanation for water anomalies.
  • The reentrance of the spinodal is disproven as a cause for water anomalies.
  • Accurate experimental data, particularly for heat capacity, is crucial for validating thermodynamic models.