Related Experiment Video
Updated: Dec 21, 2025
Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Confining Polyoxometalate Clusters into Porous Aromatic Framework Materials for Catalytic Desulfurization of
Pengyuan Wang1,2, Lingchang Jiang3, Xiaoqin Zou1
1Key Laboratory of Polyoxometalates Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.
Abstract:
Removal of notorious sulfur compounds to produce low-sulfur-content (≤10 ppm) diesel is necessary and vital for modern industry and environmental protection. A new type of inorganic-organic hybrid material has been designed and synthesized via confining molybdenum-containing polyoxometalate (POM) clusters within porous aromatic framework-1 (PAF-1) cavities named POM-PAF-1. Deep oxidative desulfurization experiments reveal that POM-PAF-1 possesses excellent reactivity under mild conditions, exemplified by a sulfur removal degree of 98.5% dibenzothiophene within 30 min at 30 °C. The improvement in oxidative desulfurization reactivity from traditional porous POM-based catalysts is owing to uniform POMs and lipophilic and porous PAF-1. The high performance of POM-PAF-1 in terms of excellent reactivity and good stability means it has potential in new heterogeneous catalysis.
More Related Videos
10:27Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
Published on: July 14, 2015
12:30Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018