Jove
Visualize
Contact Us

Related Concept Videos

Generalized Hooke's Law01:22

Generalized Hooke's Law

2.5K
The generalized Hooke's Law is a broadened version of Hooke's Law, which extends to all types of stress and in every direction. Consider an isotropic material shaped into a cube subjected to multiaxial loading. In this scenario, normal stresses are exerted along the three coordinate axes. As a result of these stresses, the cubic shape deforms into a rectangular parallelepiped. Despite this deformation, the new shape maintains equal sides, and there is a normal strain in the direction of the...
2.5K
Exponential Equations for Modeling Growth02:33

Exponential Equations for Modeling Growth

135
Exponential models are essential for describing rapid, multiplicative changes in natural systems, such as population growth. When a population doubles at regular intervals, the process can be modeled using a suitable base. For instance, a bacterial culture that doubles every three hours follows the model n(t)=n0⋅2t/3, where n(t) is the population at the time t.A more general model uses the natural base e, especially for continuous growth. This takes the form n(t)=n0⋅ert, where r is...
135
Maxwell-Boltzmann Distribution: Problem Solving01:20

Maxwell-Boltzmann Distribution: Problem Solving

2.7K
Individual molecules in a gas move in random directions, but a gas containing numerous molecules has a predictable distribution of molecular speeds, which is known as the Maxwell-Boltzmann distribution, f(v).
This distribution function f(v) is defined by saying that the expected number N (v1,v2) of particles with speeds between v1 and v2 is given by
2.7K
Clausius-Clapeyron Equation02:35

Clausius-Clapeyron Equation

61.9K
The equilibrium between a liquid and its vapor depends on the temperature of the system; a rise in temperature causes a corresponding rise in the vapor pressure of its liquid. The Clausius-Clapeyron equation gives the quantitative relation between a substance’s vapor pressure (P) and its temperature (T); it predicts the rate at which vapor pressure increases per unit increase in temperature.
61.9K
Scaling01:26

Scaling

479
In designing and analyzing filters, resonant circuits, or circuit analysis at large, working with standard element values like 1 ohm, 1 henry, or 1 farad can be convenient before scaling these values to more realistic figures. This approach is widely utilized by not employing realistic element values in numerous examples and problems; it simplifies mastering circuit analysis through convenient component values. The complexity of calculations is thereby reduced, with the understanding that...
479
Differential Form of Maxwell's Equations01:17

Differential Form of Maxwell's Equations

1.1K
James Clerk Maxwell (1831–1879) was one of the significant contributors to physics in the nineteenth century. He is probably best known for having combined existing knowledge of the laws of electricity and the laws of magnetism with his insights to form a complete overarching electromagnetic theory, represented by Maxwell's equations. The four basic laws of electricity and magnetism were discovered experimentally through the work of physicists such as Oersted, Coulomb, Gauss, and...
1.1K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same journal

The influence of chirality on the macroscopic behavior of multiferroic smectic phases.

The Journal of chemical physics·2026
Same journal

Polaron transformed canonically consistent quantum master equation.

The Journal of chemical physics·2026
Same journal

The x-ray absorption spectrum of the propargyl radical C3H3●.

The Journal of chemical physics·2026
Same journal

Transient hydroperoxyalkyl intermediates (•QOOH) in isopentane oxidation. I. Conformer- and isomer-resolved infrared spectra.

The Journal of chemical physics·2026
Same journal

Transient hydroperoxyalkyl intermediates (•QOOH) in isopentane oxidation. II. Isomer-resolved unimolecular dynamics.

The Journal of chemical physics·2026
Same journal

Quantum state-to-state dynamics studies of the C(3P) + OH(X2Π) → CO(a3Π) + H(2S) reaction based on a new HCO(12A″) potential energy surface.

The Journal of chemical physics·2026
See all related articles
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Video

Updated: Dec 21, 2025

Modeling the Size Spectrum for Macroinvertebrates and Fishes in Stream Ecosystems
07:41

Modeling the Size Spectrum for Macroinvertebrates and Fishes in Stream Ecosystems

Published on: July 30, 2019

7.9K

Generalizing the Marcus equation.

William W Parson1

  • 1Department of Biochemistry, University of Washington, Seattle, Washington 98195, USA.

The Journal of Chemical Physics
|May 17, 2020
PubMed
Summary
This summary is machine-generated.

The generalized Marcus equation refines electron-transfer rate calculations by incorporating complex factors like vibrational coupling and dephasing. This advanced model, derived from quantum-classical simulations, offers a more robust understanding of reaction dynamics.

More Related Videos

Reservoir Condition Pore-scale Imaging of Multiple Fluid Phases Using X-ray Microtomography
08:02

Reservoir Condition Pore-scale Imaging of Multiple Fluid Phases Using X-ray Microtomography

Published on: February 25, 2015

13.0K
Development of an Individual-Tree Basal Area Increment Model using a Linear Mixed-Effects Approach
04:35

Development of an Individual-Tree Basal Area Increment Model using a Linear Mixed-Effects Approach

Published on: July 3, 2020

3.6K

Related Experiment Videos

Last Updated: Dec 21, 2025

Modeling the Size Spectrum for Macroinvertebrates and Fishes in Stream Ecosystems
07:41

Modeling the Size Spectrum for Macroinvertebrates and Fishes in Stream Ecosystems

Published on: July 30, 2019

7.9K
Reservoir Condition Pore-scale Imaging of Multiple Fluid Phases Using X-ray Microtomography
08:02

Reservoir Condition Pore-scale Imaging of Multiple Fluid Phases Using X-ray Microtomography

Published on: February 25, 2015

13.0K
Development of an Individual-Tree Basal Area Increment Model using a Linear Mixed-Effects Approach
04:35

Development of an Individual-Tree Basal Area Increment Model using a Linear Mixed-Effects Approach

Published on: July 3, 2020

3.6K

Area of Science:

  • Physical Chemistry
  • Chemical Dynamics
  • Quantum Mechanics

Background:

  • The Marcus equation is a cornerstone for understanding electron-transfer reaction rates.
  • Existing models often simplify complex interactions, limiting their applicability.
  • Accurate rate calculations are crucial for fields ranging from biology to materials science.

Purpose of the Study:

  • To generalize the Marcus equation for broader applicability.
  • To incorporate larger electronic-interaction matrix elements and irregular free-energy surfaces.
  • To account for the effects of multiple vibrational modes, vibrational relaxations, and pure dephasing.

Main Methods:

  • Utilized quantum-classical molecular dynamics simulations.
  • Focused on obtaining necessary information from the system's reactant state.
  • Developed a generalized expression for the electron-transfer rate constant.

Main Results:

  • The generalized equation accommodates larger electronic-interaction matrix elements.
  • Irregular free-energy surfaces and multi-mode vibrational coupling are now included.
  • The derived rate constant expression is independent of reorganization energy, showing insensitivity to post-reaction relaxations.

Conclusions:

  • The generalized Marcus equation provides a more comprehensive framework for electron-transfer rate theory.
  • Quantum-classical molecular dynamics is effective for extracting key parameters.
  • The model's robustness allows for accurate predictions even with complex system dynamics.