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A metal-organic framework with in situ generated low-coordinate binuclear Cu(i) units as a highly effective catalyst
Ning-Yu Huang1, Hai He1, Hao Li1
1MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China. liaopq3@mail.sysu.edu.cn.
Chemical Communications (Cambridge, England)
|May 19, 2020
Abstract:
Herein, we report a metal-organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g-1 h-1) for photodriven hydrogen generation, which is attributed to the synergistic catalytic effect between the two copper ions.
