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In situ XAFS of acid-resilient iridate pyrochlore oxygen evolution electrocatalysts under operating conditions
David L Burnett1, Enrico Petrucco, Andrea E Russell
1Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, UK. r.i.walton@warwick.ac.uk.
Physical Chemistry Chemical Physics : PCCP
|May 19, 2020
Abstract:
Pyrochlore iridates (Na,Ca)2-xIr2O6·H2O are acid-stable electrocatalysts that are candidates for use in electrolysers and fuel cells. Ir LIII-edge X-ray absorption fine structure spectroscopy in 1 M H2SO4 at oxygen evolution conditions suggests the involvement of the electrons from the conduction band of the metallic particles, rather than just surface iridium reacting.

