Blue Light-promoted Carbene Transfer Reactions of Tosylhydrazones
Yingying Xu1, Guanghui Lv2, Kaichuan Yan1
1Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, Chengdu, 610041, China.
Abstract:
Metal-free photochemical carbene-transfer reactions of tosylhydrazones were developed under blue light irradiation at room temperature. This reaction constructs C-X (X=C, N, O, S) bonds and cyclopropanes from readily available and stable starting materials.
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