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Ni3Te2O2(PO4)2(OH)4, an open-framework structure isotypic with Co3Te2O2(PO4)2(OH)4
1Institute for Chemical Technologies and Analytics, Division of Structural Chemistry, TU Wien, Getreidemarkt 9/164-SC, A-1060 Vienna, Austria.
Abstract:
Single crystals of Ni3(TeO(OH)2)2(PO4)2, trinickel(II) bis[(oxidodihydoxidotellurate(IV)] bis(phosphate),were obtained by hydro-thermal synthesis at 483 K, starting from NiCO3·2Ni(OH)2, TeO2 and H3PO4 in a molar ratio of 1:2:2. The crystal structure of Ni3Te2O2(PO4)2(OH)4 is isotypic with that of Co3Te2O2(PO4)2(OH)4 [Zimmermann et al. (2011 ▸). J. Solid State Chem. 184, 3080-3084]. The asymmetric unit comprises two Ni (site symmetries , 2/m) one Te (m), one P (m), five O (three m, two 1) and one H (1) sites. The tellurium(IV) atom shows a coordination number of five, with the corresponding [TeO3(OH)2] polyhedron having a distorted square-pyramidal shape. The two NiII atoms are both octa-hedrally coordinated but form different structural elements: one constitutes chains made up from edge-sharing [NiO6] octa-hedra extending parallel to [010], and the other isolated [NiO2(OH)4] octa-hedra. The two kinds of nickel/oxygen octa-hedra are connected by the [TeO3(OH)2] pyramids and the [PO4] tetra-hedra through edge- and corner-sharing into a three-dimensional framework structure with channels extending parallel to [010]. Hydrogen bonds of medium strength between the hy-droxy groups and one of the phosphate O atoms consolidate the packing. A qu-anti-tative structure comparison between Ni3Te2O2(PO4)2(OH)4 and Co3Te2O2(PO4)2(OH)4 is made.
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