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Atomic emission spectroscopy (AES) is an analytical technique used to determine the elemental composition of a sample by analyzing the light emitted from excited atoms. In AES, atoms in a sample are excited to higher energy levels by thermal energy from high-temperature sources, such as plasma, arcs, or sparks. When these excited atoms return to lower energy states, they emit light at specific wavelengths characteristic of each element. The resulting atomic emission spectrum, which consists of...

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Sensitivity Analysis for Predicting Sub-Micron Aerosol Concentrations Based on Meteorological Parameters.

Martha A Zaidan1, Ola Surakhi2, Pak Lun Fung1

  • 1Institute for Atmospheric and Earth System Research (INAR)/Physics, University of Helsinki, FI-00560 Helsinki, Finland.

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This study developed a particle number (PN) concentration modeling framework using artificial neural networks. The models effectively estimate PN levels from meteorological data, addressing measurement gaps for air quality monitoring.

Keywords:
artificial neural networksfeed-forward neural networkmodelingparticle number concentrationsensitivity analysistime-delay neural network

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Area of Science:

  • Environmental Science
  • Atmospheric Chemistry
  • Air Quality Monitoring

Background:

  • Sub-micron aerosols, measured as particle number concentration (PN), are critical air pollutants with significant health impacts.
  • Data scarcity in PN measurements at air quality stations necessitates robust modeling approaches.
  • Developing accurate PN models is crucial for comprehensive air quality assessment.

Purpose of the Study:

  • To present a novel PN modeling framework utilizing sensitivity analysis.
  • To evaluate the performance of artificial neural networks (ANNs) for PN concentration prediction.
  • To identify optimal meteorological parameters as descriptors for PN modeling.

Main Methods:

  • A year-long aerosol measurement campaign in Amman, Jordan, was used for model development and testing.
  • Feed-forward neural networks (FFNN) and time-delay neural networks (TDNN) were employed as modeling tools.
  • Sensitivity analysis was conducted on various combinations of meteorological parameters (temperature, humidity, pressure, wind speed) as model inputs.

Main Results:

  • FFNN achieved high accuracy (R² = 0.77) for daily averaged PN data.
  • TDNN demonstrated good performance (R² = 0.66) for hourly averaged PN data.
  • Temperature, relative humidity, pressure, and wind speed were identified as key meteorological descriptors.

Conclusions:

  • The developed PN models successfully capture diurnal patterns and provide satisfactory estimations.
  • These models offer a viable solution for estimating PN concentration when direct measurements are unavailable or incomplete.
  • The framework enhances air quality monitoring capabilities by leveraging meteorological data for PN prediction.