Low-Temperature Miniemulsion-Based Routes for Synthesis of Metal Oxides

The use of miniemulsions containing chemical precursors in the disperse phase is a versatile method to produce nanoparticles and nanostructures of different chemical nature, including not only polymers, but also a variety of inorganic materials. This Minireview focuses on materials in which nanostructures of metal oxides are synthesized in processes that involve the miniemulsion technique in any of the steps. This includes in the first place those approaches in which the spaces provided by nanodroplets are directly used to confine precipitation reactions that lead eventually to oxides. On the other hand, miniemulsions can also be used to form functionalized polymer nanoparticles that can serve either as supports or as controlling agents for the synthesis of metal oxides. Herein, the description of essential aspects of the methods is combined with the most representative examples reported in the last years for each strategy.