Effect of Pd/Ce loading on the performance of Pd-Ce/γ-Al₂O₃ catalysts for toluene abatement

A single metal Pd/γ-Al₂O₃ catalyst and a bimetallic Pd-Ce/γ-Al₂O₃ catalyst were prepared by the equal-volume impregnation method to investigate the effect of CeO₂ loading on the catalytic oxidation of toluene. The specific surface area, surface morphology, and redox performance of the catalyst were characterized by N₂ desorption, scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), H₂-TPR, O₂-TPD, and electron paramagnetic resonance (EPR). The results showed that bimetal catalysts loaded CeO₂ had smaller nano-PdO particles than those of the Pd/γ-Al₂O₃ catalyst. Compared with the catalyst of 0.2Pd/γ-Al₂O₃ (percentage of mass, the same as below), the catalyst doped with 0.3CeO₂ had a stronger reduction peak, which was shifted to the low-temperature zone by more than 80 °C. The results of XPS and O₂-TPD showed that the introduction of CeO₂ provided more surface oxygen vacancy for the catalyst and enhanced its catalytic oxidation ability, and the amount of desorbed O₂ increased from 3.55 μmol/g to 8.54 μmol/g. The results of EPR were that the addition of CeO₂ increased the content of active oxygen species and oxygen vacancies on the surface of the catalysts, which might be due to the supply of electrons to the O₂ and PdO during the Ce³⁺toCe⁴⁺ conversion process. That could have accelerated the catalytic reaction process. Compared with the single precious metal catalyst, the T₁₀ and T₉₀ of the Pd-Ce/γ-Al₂O₃ catalyst were decreased by 22 °C and 40 °C, respectively.