Product-oriented Direct Cleavage of Chemical Linkages in Lignin

Lignin is one of the most important biomacromolecules in the plant biomass and the largest renewable source of aromatic building blocks in nature. Selectively producing value-added chemicals from the catalytic transformation of renewable lignin is of strategic significance and meet sustainability targets owing to the excessive consumption of non-renewable petroleum resource, but remains a long-term challenge owing to the complexity of lignin structure. This Minireview provides a summary and perspective of the extensive research that provides insight into selectively catalytic transformations of lignin and its derived monomers via directed scissor of chemical linkages (C-O and C-C bonds) with product-oriented targets. Furthermore, some challenges and opportunities of lignin catalytic transformation are provided based on existing problems in this field for readers to discuss future research directions.