Porous Graphene Oxide-Metal Ion Composite for Selective Sensing of Organophosphate Gases

Organophosphates are used as agricultural pesticides and also encountered as toxic nerve agents in chemical warfare. Accordingly, development of sensors for detecting and monitoring organophosphate vapors is highly sought after. We present a new capacitive gas sensor exhibiting remarkable specificity and sensitivity toward the organophosphate nerve gas simulants triethyl-phosphate (TEP) and dimethyl methyl phosphate and the pesticide dichlorvos. Specifically, the capacitive sensor comprises a composite porous graphene oxide matrix intercalating cobalt or nickel ions, prepared through a simple freeze-drying procedure. We demonstrate that the porous graphene oxide/metal ion electrode undergoes fast capacitance changes only upon exposure to organophosphate vapors. Moreover, the sensor exhibits extraordinary sensitivity upon interactions with TEP. Detailed mechanistic analyses, carried out in comparison to porous graphene oxide coupled to other transition metal ions, reveal that the remarkable sensing properties of the Co²⁺ or Ni²⁺/porous graphene oxide systems likely arise from the distinct mode of metal ion incorporation into the graphene oxide host matrix and substitution of metal-complexed water ligands with organophosphate molecules. The new metal ion/porous graphene oxide capacitive sensor may be employed for alerting and monitoring organophosphate gases in different environments.