Dynamic Interfacial Regulation by Photodeformable Azobenzene-Containing Liquid Crystal Polymer Micro/Nanostructures

Photoresponsive materials offer local, temporal, and remote control over their chemical or physical properties under external stimuli, giving new tools for interfacial regulation. Among all, photodeformable azobenzene-containing liquid crystal polymers (azo-LCPs) have received increasing attention because they can be processed into various micro/nanostructures and have the potential to reversibly tune the interfacial properties through chemical and/or morphological variation by light, providing effective dynamic interface regulation. In this feature article, we highlight the milestones in the dynamic regulation of different interfacial properties through micro/nanostructures made of photodeformable azobenzene-containing liquid crystal polymers (azo-LCPs). We describe the preparation of different azo-LCP micro/nanostructures from the aspects of materials and processing techniques and reveal the importance of mesogen orientation toward dynamic interfacial regulation. By introducing our recently developed linear azo-LCP (azo-LLCP) with good mechanical and photoresponsive performances, we discuss the challenge and opportunity with respect to the dynamic light regulation of two- and three-dimensional (2D/3D) micro/nanostructures to tune their related interfacial properties. We have also given our expectation toward exploring photodeformable micro/nanostructures for advanced applications such as in microfluidics, biosensors, and nanotherapeutics.