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Updated: Jul 17, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
A Visible-Light-Powered Polymerization Method for the Immobilization of Enantioselective Organocatalysts into
Rico Warias1, Daniele Ragno2, Alessandro Massi2
1Institute of Analytical Chemistry, Leipzig University, Linnéstraße 3, 04103, Leipzig, Germany.
Abstract:
A versatile one-step photopolymerization approach for the immobilization of enantioselective organocatalysts is presented. Chiral organocatalyst-containing monoliths based on polystyrene divinylbenzene copolymer were generated inside channels of microfluidic chips. Exemplary performance tests were performed for the monolithic Hayashi-Jørgensen catalyst in continuous flow, which showed good results for the Michael addition of aldehydes to nitroalkenes in terms of stereoselectivity and catalyst stability with minimal consumption of reagents and solvents.
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