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Surface Tension of Dielectric-Air Interfaces
Rajeev Kumar1,2, Murugappan Muthukumar3
1Computational Sciences and Engineering Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States.
Abstract:
Analytical and semianalytical expressions for the surface tension of dielectric-air interfaces are presented after considering local and nonlocal dielectric effects near interfaces. It is shown that the nonlocal effects of dielectrics are significant for highly polar dielectric fluids such as water. Far from the interface, nonlocal dielectric effects are shown to cause not only the oscillatory potential of the mean force but also a reversal of sign at intermediate distances.
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