Inhibition of polychlorinated dibenzo-p-dioxins and dibenzofurans by phosphorus-containing compounds in model fly ash

Waste incineration is a preferred method in China to dispose the municipal solid waste, but controlling the production of highly toxic polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans effectively during incineration is both challenging and imperative. In this study, the suppression of PCDD/Fs by various phosphorus-containing compounds was explored, and the mechanisms responsible for the inhibition were studied in detail. The experiments took place in a lab-scale vertical tubular reactor at 350 °C under a simulated flue gas (12 vol% O₂ in N₂ flow), and both the off-gases and residues were collected for PCDD/Fs analysis. The scanning electron microscopy and energy-dispersive X-ray spectroscopy were used to characterize the reaction residues. The experimental results revealed that NH₄H₂PO₄ and (NH₄)₂·HPO₄ showed the highest inhibitory effect (57.2% and 57.3%, respectively) on the PCDD/Fs formation, followed by CaHPO₄ with inhibition efficiency of 39.1%. In contrast, KH₂PO₄ and K₂HPO₄ barely inhibited the generation of the PCDD/Fs. The inhibitory effect of NH₄H₂PO₄ and (NH₄)₂·HPO₄ was similar to that of nitrogen-based inhibitors. At the same time, it was proven that the inhibitory activity of CaHPO₄ might be due to the reaction of it with Cu²⁺ forming stable compounds.