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Related Concept Videos

Flame Photometry: Overview01:02

Flame Photometry: Overview

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Flame photometry, also known as flame emission spectrometry, is a technique used for the qualitative and quantitative analysis of elements present in a sample using a flame as the source of excitation energy. The concept of flame photometry was realized in the early 1860s by Kirchhoff and Bunsen, who discovered that specific elements emit characteristic radiation when excited in flames. The first instrument developed for this purpose was used to measure sodium (Na) in plant ash using a Bunsen...
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Temperature Measurement Sites01:14

Temperature Measurement Sites

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A thermometer measures body temperature. The common sites for measuring body temperature are the oral cavity, axillary region, temporal artery, and skin surface, such as the forehead, abdomen, and axilla. True core body temperature is assessed in the rectum, tympanic membrane, pulmonary artery, esophagus, and urinary bladder.
Oral: When assessing oral temperature, the thermometer tip should be placed under the tongue in the posterior sublingual pocket. It offers accurate readings and can be...
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Atomic Spectroscopy: Effects of Temperature01:27

Atomic Spectroscopy: Effects of Temperature

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Atomization, converting samples into gas-phase atoms and ions, is essential for atomic spectroscopy. The flame temperature required for atomization affects the efficiency of the atomic spectroscopic methods by increasing the atomization efficiency and the relative population of the excited and ground states.
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature...
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Flame Photometry: Lab01:16

Flame Photometry: Lab

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In a flame photometer, when a solution like potassium chloride is aspirated into the flame, the solvent evaporates, leaving behind dehydrated salt. This salt dissociates into free gaseous atoms in their ground state. Some of these atoms absorb energy from the flame, leading to their excitation. The excited atoms return to the ground state, emitting photons at characteristic wavelengths. Because only electronic transitions are involved, the resulting emission lines are very narrow. The intensity...
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Thermometers and Temperature Scales01:22

Thermometers and Temperature Scales

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Any physical property that depends consistently and reproducibly on temperature can be used as the basis of a thermometer. For example, volume increases with temperature for most substances. This property is the basis for the common alcohol thermometer and the original mercury thermometers. Other properties used to measure temperature include electrical resistance, color, and the emission of infrared radiation.
As many physical properties depend on temperature, the variety of thermometers is...
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Equipments Used to Measure Body Temperature01:13

Equipments Used to Measure Body Temperature

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Body temperature can be assessed using various devices and measured in Celsius or Fahrenheit.
Glass-bulb Thermometer:
Glass-bulb thermometers are hollow glass tubes with a bulb tip containing liquid such as ethanol or mercury. Historically, glass bulb mercury thermometers were the standard device to measure body temperature. Today, mercury thermometers are prohibited in many countries due to the hazardous effects of mercury and the risk of exposure if the glass bulb breaks. In general,...
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Updated: Dec 20, 2025

Laser-heating and Radiance Spectrometry for the Study of Nuclear Materials in Conditions Simulating a Nuclear Power Plant Accident
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Surface temperature estimation in determined multi-wavelength pyrometry systems.

António Araújo1, Rui Silva1

  • 1Faculdade de Engenharias e Tecnologias, Universidade Lusíada Norte, 4760-108 Vila Nova de Famalicão, Portugal.

The Review of Scientific Instruments
|June 4, 2020
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Summary
This summary is machine-generated.

Ridge regression significantly improves multi-wavelength pyrometry accuracy. This statistical method enhances temperature estimation, especially with more pyrometer channels, reducing errors substantially.

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Area of Science:

  • Thermodynamics
  • Optical Engineering
  • Statistical Modeling

Background:

  • Multi-wavelength pyrometry relies on Wien's law for temperature estimation.
  • Modeling surface spectral emissivity with polynomial functions presents accuracy challenges.
  • Simple linear models can yield unacceptably low temperature estimates in pyrometry.

Purpose of the Study:

  • To develop and evaluate a multi-wavelength pyrometry model.
  • To investigate the impact of emissivity functions on temperature estimation accuracy.
  • To apply ridge regression for improving temperature estimation in multi-wavelength pyrometry.

Main Methods:

  • Derived a multi-wavelength pyrometry model using Wien's law.
  • Modeled surface spectral emissivity as a polynomial function of wavelength.
  • Simulated temperature outputs using various emissivity functions and computed estimates via a simple linear model.
  • Applied ridge regression to address ill-posed systems and enhance accuracy.

Main Results:

  • Simple linear models showed variable accuracy depending on emissivity functions.
  • Ridge regression substantially increased temperature estimation accuracy, particularly for higher-order systems.
  • Estimation errors decreased by approximately 52% with 3 to 20 channels.
  • Errors reduced by over 65% using ridge regression (20 channels) compared to the linear model (2 channels).

Conclusions:

  • Ridge regression offers a robust solution for improving multi-wavelength pyrometry accuracy.
  • The effectiveness of ridge regression increases with the number of pyrometer channels.
  • This statistical technique holds significant potential for precise high-temperature measurements.