A cryogenic ice setup to simulate carbon atom reactions in interstellar ices
D Qasim1, M J A Witlox2, G Fedoseev1
1Laboratory for Astrophysics, Leiden Observatory, Leiden University, P.O. Box 9513, NL-2300 RA Leiden, The Netherlands.
The Review of Scientific Instruments
|June 4, 2020
Summary
A new carbon atom beam source was developed to study interstellar ice reactions. This tool enables the investigation of complex organic molecule formation in simulated interstellar cloud conditions.
Area of Science:
- Astrochemistry
- Physical Chemistry
- Materials Science
Background:
- Interstellar ices are crucial for complex organic molecule (COM) formation.
- Previous experimental setups lacked a dedicated carbon atom beam for simulating interstellar conditions.
Purpose of the Study:
- To design and implement a customized carbon atom beam source.
- To integrate this source into an existing ultrahigh vacuum (UHV) setup (SURFRESIDE^2).
- To enable the study of solid-state reaction routes in interstellar ices.
Main Methods:
- Development of a novel carbon atom beamline.
- Integration into the SURFRESIDE^2 UHV apparatus.
- Quantitative performance assessment using a C + 18O2 reaction experiment.
- Computational derivation of activation barriers.
Main Results:
- Successful implementation of a third atom (C) beamline, creating a unique experimental system.
- Characterization of the carbon atom beam's flux, temperature, and beam size.
- Experimental validation of the carbon beam's performance in a model reaction.
Conclusions:
- The developed carbon atom beam source is well-suited for simulating interstellar cloud conditions.
- This system facilitates the study of solid-state COM formation via carbon atom reactions.
- The setup advances research into the origins of interstellar organic chemistry.
Related Concept Videos
Phase Transitions: Melting and Freezing
14.4K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
14.4K
Cryo-electron Microscopy
4.0K
Conventional electron microscopy (EM) involves dehydration, fixation, and staining of biological samples, which distorts the native state of biological molecules and results in several artifacts. Also, the high-energy electron beam damages the sample and makes it difficult to obtain high-resolution images. These issues can be addressed using cryo-EM, which uses frozen samples and gentler electron beams. The technique was developed by Jacques Dubochet, Joachim Frank, and Richard Henderson, for...
4.0K
Atomic Absorption Spectroscopy: Atomization Methods
1.3K
Atomic Absorption Spectroscopy (AAS) atomizes samples through flame atomization or electrothermal atomization. Flame atomization typically involves a nebulizer and spray chamber assembly to combine the sample with a fuel–oxidant mixture, creating a fine aerosol mist that enters a burner. Typically, the fuel and oxidant are combined in an approximately stoichiometric ratio. However, for atoms that are easily oxidized, a fuel-rich mixture may be more advantageous. Only about 5% of the...
1.3K
Atomic Spectroscopy: Effects of Temperature
781
Atomization, converting samples into gas-phase atoms and ions, is essential for atomic spectroscopy. The flame temperature required for atomization affects the efficiency of the atomic spectroscopic methods by increasing the atomization efficiency and the relative population of the excited and ground states.
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature...
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature...
781
Phase Transitions: Vaporization and Condensation
20.3K
The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules...
20.3K
Intermolecular Forces
68.1K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
68.1K


