A Fluorescent Chemosensor Based on Schiff Base for the Determination of Zn²⁺, Cd²⁺and Hg²

Metal complexes were obtained by the reaction of zinc, cadmium and mercury(II) salts with Schiff base HL (N(salicylidene)benzylamine). HL was synthesized by the condensation reaction of benzylamine and 2-hydroxybenzaldehyde. The fluorescence properties of the Schiff base and its metal complexes were studied in ethanol-water solutions. HL was examined for its utility as a fuorescent chemosensor for the determination of Zn²⁺, Cd²⁺ and Hg²⁺ in aqueous samples. The HL chemosensor was found to be sensitive to Zn²⁺, Cd²⁺ and Hg²⁺ than some metal ions and its complexes emitted strong fluorescence at 452 nm for Zn²⁺ at 474 nm for Cd²⁺ and at 491 nm for Hg²⁺, respectively. It was determined that HL forms complexes with a ratio of 2:1 for Zn²⁺ and Hg²⁺ and with a ratio of 1:1 for Cd²⁺ by Job plots. For the detection of Zn²⁺, Cd²⁺ and Hg²⁺ in aqueous samples, pH, solvent type and ligand concentration were optimized for an analytical method based on HL chemosensor. HL gave a wide range of linearity with Zn²⁺, Hg²⁺ and Cd²⁺, the limit of detection was found to be 2.7 × 10^-7 M, 7.5 × 10^-7 M and 6.0 × 10^-7 M, respectively.