Drivers of seasonal and annual air pollution exposure in a complex urban environment with multiple source...

Outdoor air pollution is a global health concern, but detailed exposure information is still limited for many parts of the world. In this study, high-resolution exposure surfaces were generated for annual and seasonal fine particulate matter (PM_2.5), coarse particulate matter (PM₁₀), and carbon monoxide (CO) for the Greater Beirut Area (GBA), Lebanon, an urban zone with a complex topography and multiple source contributions. Land use regression models (LUR) were calibrated and validated with monthly data collected from 58 locations between March 2017 and March 2018. The annual mean (±1 SD) concentrations of PM_2.5, PM₁₀, and CO across the monitoring locations were 68.1 (±15.7) μg/m³, 83.5 (±19.5) μg/m³, and 2.48 (±1.12) ppm, respectively. The coefficients of determination for LUR models ranged from 56 to 67% for PM_2.5, 44 to 63% for the PM₁₀ models, and 50 to 60% for the CO. LUR model structures varied significantly by season for both PM_2.5 and PM₁₀ but not for CO. Traffic emissions were consistently the main source of CO emissions throughout the year. The relative importance of industrial emissions and power generation sources towards predicted PM levels increased during the hot season while the contribution of the international airport diminished. Moreover, the complex topography of the study area along with the seasonal changes in the predominant wind directions affected the spatial predicted concentrations of all three pollutants. Overall, the predicted exposure surfaces were able to conserve the inter-pollution correlations determined from the field monitoring campaign, with the exception of the cold season. Our pollution surfaces suggest that the entire population of Beirut is regularly exposed to concentrations exceeding the World Health Organization (WHO) air quality standards for both PM_2.5 and PM₁₀.