Universal scaling of adsorption of nonionic surfactants on carbonates using cloud point temperatures

Nonionic surfactants alter the wettability of oil-wet carbonate surfaces to a water-wet state. The degree of surfactant adsorption is expected to determine the extent of the wettability alteration. Furthermore, the structure of the hydrophobic and hydrophilic units of the surfactant should affect the degree of adsorption and correlate with the wettability alteration.

The adsorption on Indiana limestone was measured for nonionic surfactants with two different types of hydrophobic units and hydrophilic polyethoxylate units ranging from 15 to 40 mers. Measurements were conducted for several surfactant concentrations and temperatures.

Adsorption increased with temperature and for surfactants with fewer hydrophilic groups. The adsorption occurs as micelles rather than individual surfactant molecules. An increase in adsorption is observed for the more hydrophobic surfactants at higher temperature and is attributed to the increase in micelle sizes. Adsorption collapses onto a universal curve as a function of the difference between cloud point of the surfactant and system temperature. At the same time wettability alteration was found to have a direct correlation with surfactant adsorption. These findings are critical for judicious selection of nonionic surfactants for analysis and design of wettability alteration for oil reservoirs.