Pyrolysis of Biomass Impregnated With Ammonium Dihydrogen Phosphate for Polygeneration of Phenol and Supercapacitor Electrode Material

A new method was proposed for polygeneration of phenol and supercapacitor electrode material from pyrolysis of biomass impregnated with ammonium dihydrogen phosphate (NH₄H₂PO₄). The pyrolysis experiments were executed to demonstrate the product distributions under different NH₄H₂PO₄-to-poplar (PA-to-PL) ratios and pyrolysis temperatures in a lab-scale device. The results revealed that the phenol yield attained its optimal value of 4.57 wt% with a satisfactory selectivity of 20.09% at 500°C under PA-to-PL ratio of 0.6. The pyrolytic solid product obtained at this condition was then subjected to high temperature activation directly without additional activators to prepare N and P co-doped activated carbon (NPAC) as supercapacitor. The physicochemical analysis of NPAC showed that the N and P contents in NPAC reached 3.75 and 3.65 wt%, respectively. The electrochemical experiments executed in a three-electrode system indicated that the NPAC exhibited promising electrochemical performance with a satisfactory capacitance of 181.3 F g^-1 at 1 A g^-1.