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Published on: October 5, 2018
Thermal behaviour of hindered rotor in static electric and laser field
Sumana Devi1, Ashish Tyagi2, Vinod Prasad2
1Department of Physics and Astrophysics, University of Delhi, Delhi 110007, India; Department of Physics, Miranda House College, University of Delhi, Delhi 110007, India.
Abstract:
We solve exactly the time independent Schrödinger equation (TISE) for hindered rotor confined in well shaped potential. Afterwards, the confined system is subjected to interact with laser and static electric field. TISE for the dressed confined rotor is solved using standard numerical method to get energy spectrum and eigenfunctions. Dependence of orientation and alignment parameters on static electric field and confining potential is studied. We also compute thermal properties like entropy and heat capacity of the system under consideration using canonical partition within statistical thermodynamic formalism. We have also studied the effect of external field parameters, confinement strength and temperature on these thermal properties.
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