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Decoupling of itinerant and localized d-orbital electrons in the compound Sc0.5Zr0.5Co
Jin Si1, Xinwei Fan1, Enyu Wang2
1National Laboratory of Solid State Microstructures and Department of Physics, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, People's Republic of China.
Abstract:
By using the arc-melting method, we successfully synthesize the compound Sc0.5Zr0.5Co with the space group ofPm-3m. Both the resistivity and magnetic susceptibility measurements reveal a phase transition at about 86 K. This transition might be attributed to the establishment of an antiferromagnetic order. The magnetization hysteresis loop measurements in wide temperature region show a weak ferromagnetic feature, which suggests a possible canted arrangement of the magnetic moments. Bounded by the phase transition temperature, the resistivity at ambient pressure shows a change from Fermi liquid behavior to a super-linear behavior as temperature increases. By applying pressure up to 32.1 GPa, the transition temperature does not show a clear change and no superconductivity is observed above 2 K. The density functional theory calculations simulate the antiferromagnetic order and reveal a gap between the spin-up and spin-down d-orbital electrons. This kind of behavior may suggest that the antiferromagnetic order in this compound originates from the localized d-electrons which do not contribute to the electric conduction. Thus the itinerant and localized d-orbital electrons in the compound are decoupled.
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