Characteristics of chlorinated and brominated polycyclic aromatic hydrocarbons in the Pearl River Estuary

The spatial distribution of halogenated polycyclic aromatic hydrocarbons (H-PAHs) (8 chlorinated PAHs (Cl-PAHs) and 9 brominated PAHs (Br-PAHs)), in the Pearl River Estuary (PRE) was investigated. The total concentrations of 17H-PAHs in sediment samples were ranged from 1.4 ng g^-1 to 40.9 ng g^-1 with an average concentration of 14.7 ng g^-1. The average H-PAH concentration in the suspended particulate matters (SPMs) (475.6 ng g^-1) was 30 times higher than that in the sediments (14.7 ng g^-1), and H-PAHs were rarely detected in the aqueous phase. The dominant H-PAHs in sediments were 9,10-dichloroanthracene (31.2%) and 9-chlorophenanthrene (32.0%); 2/9-chlorofluorene (27.4%) was prominent in surface SPMs, while no significant dominant congeners were found in bottom SPMs. Principal component analysis showed that the congener profiles of H-PAHs in sediments were different from those of SPMs especially for surface SPM samples which might be caused by point source discharges of H-PAHs from the coast of the PRE. In general, riverine inputs were the major source of H-PAHs in the PRE, and SPMs were important carriers for transporting H-PAHs. Diagnostic analyses showed that the H-PAHs might originate from waste incineration and automobile emissions in the Pearl River Delta (PRD).