Effect of doping different Si source on Ca-P bioceramic coating fabricated by laser cladding

The doping of silicon (Si) has been proved to improve the bioactivity of Ca-P ceramics. In light of this thinking, in the present study, Ca-P coatings with La₂O₃ by addition of 10 wt% SiO₂ and 10 wt% diatomaceous earth (DE) were fabricated by laser cladding on Ti6Al4V, respectively. Coating doped without Si was also fabricated as the comparison group for the experiment. The effect of two different Si sources on the surface morphology, microstructure, microhardness, and bioactivity was systematically studied. The experimental results show that the Si-doped coating is of rough surface morphology, and the addition of DE significantly reduces the number of cracks and improves the microhardness. The X-ray diffraction results reveal that the amount of bioactive phase tricalcium-phosphate (TCP) and hydroxyapatite (HA) reaches maximum in the DE-doped coating. After soaking in simulated body fluid (SBF), the precipitate of bone-like apatite in the DE-doped coating is significantly higher than that of the other coatings.