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Updated: Dec 18, 2025
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Mechano-assisted synthesis of an ultramicroporous metal-organic framework for trace CO2 capture
Zhaoqiang Zhang1, Qi Ding1, Shing Bo Peh2
1Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China. cuixl@zju.edu.cn.
Abstract:
An ultramicroporous MOF, ZU-36-Ni (GeFSIX-3-Ni) is obtained for the first time via a mechanochemical-assisted approach. The material exhibits excellent performance for trace CO2 capture (1.07 mmol g-1 at 400 ppm) and benchmark 50/50 CO2/CH4 selectivity of 930, which is proven by dynamic breakthrough tests.
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