Adsorption of toxic dye Eosin Y from aqueous solution by clay/carbon composite derived from spent bleaching earth

The environmentally friendly clay/carbon composite (SBE/C) was prepared by one-step pyrolysis under N₂ atmosphere at 700°C of spent bleaching earth (SBE) from the industrial waste of the refined oil industry. SBE/C was tested to remove anionic dye Eosin Y from aqueous water. The results revealed that SBE/C had larger specific surface area than SBE, and the equilibrium adsorption capacity of SBE/C (11.15 mg/g) was about 3 times than that of SBE (4.04 mg/g). The adsorption process was found to be exothermic and spontaneous. The adsorption capacity of SBE/C was independent on pH (5-12), and exhibits satisfactorily recyclable performance. Combined with characterization analysis, the adsorption mechanism likely includes electrostatic interaction, hydrogen bonding, hydrophobic interaction, halogen bonding, and π-π interaction. Overall, this exploration of SBE/C might open a window to the design of an efficient and low-cost adsorbent for Eosin Y dye elimination from wastewater. PRACTITIONER POINTS: The resource utilization of industrial waste SBE was achieved. SBE/C was synthesized and tested to adsorb Eosin Y for the first time. SBE/C had characteristics with porous structure and large surface area. pH had little effect on adsorption capacity of SBE/C for Eosin Y. SBE/C exhibited potential for dye elimination from wastewater.