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Construction of Chiral "Triple-Decker" Nd(III) Nanocluster with High NIR Luminescence Sensitivity toward Co(II)
Xia Liu1, Yanan Ma1, Xiaoping Yang1
1College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China.
Inorganic Chemistry
|June 23, 2020
Abstract:
One Nd(III) complex [Nd3L3(OAc)3] (1) was synthesized from a conjugate Schiff base ligand H2L. It shows a chiral "triple-decker" structure (1.1 × 1.2 × 1.8 nm) with Nd(III) ions sandwiched between the Schiff base ligands. 1 exhibits NIR Nd(III) luminescence, and the LMET efficiency is calculated to be 13.8%. It displays high luminescence sensitivity and selectivity to Co(II). The KSV value and LOD of 1 to Co(II) are 9.96 × 104 M-1 and 0.97 μM, respectively.

