Tailoring the Self-Healing Properties of Conducting Polymer Films

The conducting polymer polyethylenedioxythiophene doped with polystyrene sulfonate (PEDOT:PSS) has received great attention in the field of wearable bioelectronics due to its tunable high electrical conductivity, air stability, ease of processability, biocompatibility, and recently discovered self-healing ability. It has been observed that blending additives with PEDOT:PSS or post-treatment permits the tailoring of intrinsic polymer properties, though their effects on the water-enabled self-healing property have not previously been established. Here, it is demonstrated that the water-enabled healing behavior of conducting polymers is decreased by crosslinkers or by acid post-treatment. Organic dopants of PEDOT have high water swelling ratios and lead to water-enabled healing, while inorganic dopants fail in the healing of PEDOT. The water-enabled healing of two isolated PEDOT:PSS squares with a 5 µm width gap and a thickness less than 1 µm is shown. This work will help pave the way for the further development of conducting polymer-based self-healable bioelectronics and flexible and stretchable electronics.