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How Universal Is the Wetting Aging in 2D Materials.

Xuan Chen1, Zhibin Yang2, Shizhe Feng3

  • 1Department of Mechanical Engineering, City University of Hong Kong, Hong Kong 999077, China.

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|June 25, 2020
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Summary

Airborne contamination causes 2D indium selenide (InSe) films to age, becoming more hydrophobic. This wetting aging effect appears general across various substrates and may apply to many 2D materials.

Keywords:
2D materialsInSeairborne contaminationhydrophobizationwetting aging effect

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Area of Science:

  • Materials Science
  • Surface Science
  • Nanotechnology

Background:

  • Two-dimensional (2D) materials like graphene, WS2, and MoS2 on silicon substrates show aging and hydrophobicity due to airborne contaminants.
  • The ubiquity and specific mechanisms of this wetting aging are not fully understood.

Purpose of the Study:

  • To investigate the general nature of hydrophilic-to-hydrophobic wetting aging in 2D indium selenide (InSe) films.
  • To explore the influence of substrates and film thickness on this aging phenomenon.
  • To identify the adsorbed species responsible for wetting aging.

Main Methods:

  • Synthesis of 2D InSe films on diverse substrates (silicon, glass, nickel, copper, aluminum oxide).
  • Characterization of wetting properties (hydrophilicity/hydrophobicity) over time.
  • Analysis of adsorbed surface contaminants using surface-sensitive techniques.

Main Results:

  • A significant hydrophilic-to-hydrophobic wetting aging was observed in 2D InSe films.
  • This aging was independent of the substrate material but sensitive to film thickness.
  • Airborne contaminants, particularly those with alkyl chains, were identified as the cause.

Conclusions:

  • Wetting aging of 2D InSe films by airborne contamination is a general phenomenon.
  • The findings suggest that wetting aging might be a universal characteristic of many 2D materials.
  • Understanding this aging is crucial for the stability and application of 2D materials.