Simultaneously enhanced removal and stepwise recovery of atrazine and Pb(II) from water using β-cyclodextrin...

Heavy metals and pesticides often coexist in contaminated water, while their potential competition behaviors make the adsorptive removal more challenging. Thus, decorating an adsorbent with independent functional sites could be a promising alternative to radically prevent the competitive process for improving the adsorption performance. Herein, β-cyclodextrin functionalized rice husk-based cellulose (β-CD@RH-C) was designed and applied for synchronous removal of atrazine and Pb(II). The characterization results supported the successful grafting of β-cyclodextrin onto the cellulose. The β-CD@RH-C presented a pH-dependent adsorption performance for Pb(II) with a theoretical monolayer adsorption capacity of 283.00 mg/g, while was mostly unrelated to pH for atrazine adsorption with a heterogeneous uptake of 162.21 mg/g in the mono-component system. Most importantly, the β-CD@RH-C could efficiently achieve simultaneous removal of atrazine and Pb(II) via avoiding their competitive behaviors, which was due to the different adsorption mechanisms for atrazine (i.e. host-guest interaction) and Pb(II) (i.e. complexation and electrostatic interaction). Moreover, the adsorbed atrazine and Pb(II) could be sequentially desorbed with slight decrease in the adsorption performance of β-CD@RH-C even after four cycles in the atrazine-Pb(II) multi-component system. All these results suggested β-CD@RH-C to be a tailored adsorbent with high-performance elimination of co-existing heavy metals and organic pollutants in water.