Removal of phosphate at low concentration from water by porous PVA/Al₂O₃ composites

The porous polyvinyl alcohol (PVA)/Al₂O₃ composite by supporting activated alumina on the cross-linked network of PVA has been successfully prepared and its property for the removal of phosphate in aqueous solution was also evaluated. The structure of the PVA/Al₂O₃ was examined by scanning electron microscopy. It showed that the activated alumina particles with an average size of 1 μm were evenly dispersed and fixed in the cross-linked network structure of PVA. The effects of adsorption time, solution temperature, pH, initial concentration of phosphate, Al₂O₃ loading rate, dosage and coexisting ions on the phosphate removal were further studied. The results showed that the highest removal phosphate efficiency of 95% can be obtained with the Al₂O₃ loading rate of PVA/Al₂O₃ being 60 wt.% at pH of 4 at 30 °C. The maximum adsorption capacities of $$ by PVA/Al₂O₃ suggested by the Langmuir isothermal model was 10.12 mg/g. The adsorption process of phosphate can be fit well with a pseudo-second-order model (R² = 0.9900). The PVA/Al₂O₃ composite exhibited a high selective adsorption of phosphate in the presence of commonly coexisting anions except the obvious effect of $$ in water. Meanwhile, the PVA/Al₂O₃ composite can be easily separated and recovered due to the granulation of adsorbent. PVA/Al₂O₃ composite also shows the excellent properties of regeneration and recycling use with the removal efficiency of phosphate was 88.93%, 88.38% and 94.34% after three cycles, respectively. It can be proposed that the PVA/Al₂O₃ composite is a promising recyclable adsorbent for removing phosphate at low concentration from aqueous solution.