Utilisation of environmentally friendly okara-based biosorbent for cadmium(II) removal

Heavy metals released by various industries are among the major pollutants found in water resources. In this research, biosorption technique was employed to remove cadmium (Cd²⁺) from an aqueous system using a novel biosorbent developed from okara waste (OW), a residue from soya bean-based food and beverage processing. Characterisation results revealed that the OW biosorbent contained functional groups such as hydroxyl-, carboxyl- and sulphur-based functional groups, and the surface of the biosorbent was rough with multiple fissures which might be the binding sites for the pollutant. The effects of dosage, solution pH, initial Cd²⁺ concentration, temperature and contact time were investigated using batch adsorption mode. The biosorption equilibrium and kinetic were best described by the Langmuir and Elovich models, respectively. The maximum biosorption capacities predicted by the Langmuir model were 10.91-14.80 mg/g at 30-70 °C, and the biosorption process was favourable as evident from 0 < R_L < 1. The uptake of Cd²⁺ by the OW biosorbent was spontaneous and endothermic. The plausible biosorption mechanisms of this study could be ionic exchange, hydrogen bonding and electrostatic interactions. The Cd²⁺ loaded OW biosorbent could be regenerated using 0.4 M of HCl solution and regeneration was studied for 4 adsorption-desorption cycles. The present investigation supported that OW can be reused as a value-added biosorbent product for the removal of Cd²⁺ from the contaminated water.