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Updated: Aug 19, 2026

Origami Inspired Self-assembly of Patterned and Reconfigurable Particles
Published on: February 4, 2013
Electron-Transfer-Induced Self-Assembly of a Molecular Tweezer Platform
Khushabu Thakur1, Denan Wang1, Saber Mirzaei1
1Department of Chemistry, Marquette University, Milwaukee, WI, 53201-1881, USA.
Abstract:
The design and synthesis of a new molecular tweezer (T-tmp) with electron-rich pincers are reported. The stable monocationic radicals and self-assembled dimeric radicals of this molecular tweezer platform were prepared by chemical oxidative titration. With the aid of DFT calculations, it was found that the dimeric radicals with syn-syn-syn conformer has the most stable structure, with the hole primarily delocalized between parallel stacked pyrenyl groups.
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