Bound states and symmetry breaking of the ring C₂₀ ^- anion

Determining the geometry of carbon rings is an ongoing challenge. Based on our calculations at a state-of-the-art level, we found that the C₂₀ ^- ring possesses five bound electronic states, including a superatomic state, which is the first superatomic state found for a ring. The nature of these electronic states is discussed. Our calculation reveals a symmetry breaking of the C₂₀ ^- ring anion ground electronic structure occurring upon attaching an electron to the neutral ring. The discussion of the possible symmetry breaking mechanisms indicates that the shrinking and distortion of the ring upon electron attachment, leading to the symmetry breaking, is a result of the interplay between the symmetry breaking and the totally symmetric modes. The discussion enriches the palette of possible symmetry breaking phenomena in carbon clusters.