Toward monitoring the dissipative vibrational energy flows in open quantum systems by mixed quantum-classical...

In open quantum system dynamics, rich information about the major energy relaxation channels and corresponding relaxation rates can be elucidated by monitoring the vibrational energy flow among individual bath modes. However, such calculations often become tremendously difficult as the complexity of the subsystem-bath coupling increases. In this paper, we attempt to make this task feasible by using a mixed quantum-classical method, the Poisson-bracket mapping equation with non-Hamiltonian modification (PBME-nH) [H. W. Kim and Y. M. Rhee, J. Chem. Phys. 140, 184106 (2014)]. For a quantum subsystem bilinearly coupled to harmonic bath modes, we derive an expression for the mode energy in terms of the classical positions and momenta of the nuclei, while keeping consistency with the energy of the quantum subsystem. The accuracy of the resulting expression is then benchmarked against a numerically exact method by using relatively simple models. Although our expression predicts a qualitatively correct dissipation rate for a range of situations, cases involving a strong vibronic resonance are quite challenging. This is attributed to the inherent lack of quantum back reaction in PBME-nH, which becomes significant when the subsystem strongly interacts with a small number of bath modes. A rigorous treatment of such an effect will be crucial for developing quantitative simulation methods that can handle generic subsystem-bath coupling.