Multi-mode fluorescence sensing detection based on one core-shell structure quantum dots via different types of...

Multi-target sensing completed with single chemosensor is cost-effective and pretty attractive for the analysis of multiple analytes in single sample. CdTe/CdS QDs show high fluorescence quantum yield as a probe for the sensing purpose, but only single target is often detected. Here we proposed that three kinds of different response mechanisms were realized using CdTe/CdS QDs with the simultaneous sensing of Fe³⁺, Cr₂O₇^2-, and IO₃^- as model. The specific binding affinity was used to detect Fe³⁺ with the photo-induced electron transfer (PET) mechanism. CdTe/CdS QDs showed intensive fluorescent response to Cr₂O₇^2- owing to the inner filter effect (IFE). IO₃^- is an oxidant and reacts to surface functional groups of CdTe/CdS QDs with oxidation quenching (OQ) mechanism for the selective detection of IO₃^-. The three targets recorded with the three mechanisms were obviously clustered even they were tested at different concentrations. Thus, the targets could be differentiated with each other through their different responses of PET, IFE, and OQ. The linear ranges for the selective detection of Fe³⁺, Cr₂O₇^2-, and IO₃^- were 5.0-100.0, 20.0-140.0 and 1.0-80.0 μM, with the limits of detection as low as 4.1, 9.7, and 0.9 μM, respectively. The proposed methods were satisfactorily applied to accurately detect Fe³⁺, Cr₂O₇^2-, and IO₃^- in real samples and it was further detected iodate and the total amount of iodine in table salt samples. The proposed multi-target detection strategy with the single fluorescence single from single QDs will stimulate the application of the other matrix with abundant response with enhance sensing efficiency.