Related Experiment Video
Updated: Dec 15, 2025

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Pressure Effect on Electronic and Excitonic Properties of Purely J-Aggregated Monolayer Organic Semiconductor
Ruiping Li1, Meng Wang1, Huijuan Zhao2
1Key Laboratory of Flexible Electronics & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211816, China.
Abstract:
Different from monolayer inorganic semiconductors, such as transition metal dichalcogenides, monolayer organic semiconductors derived from perylene have attracted much attention because of their strong absorption and bright photoluminescence (PL). Pressure has proved to be an effective tool in probing the exciton behavior in monolayer semiconductors. Here, by studying the high-pressure behavior of purely J-aggregated monolayer organic semiconductors experimentally and theoretically, we find a red shift of PL spectra due to a decrease of band gap, which is consistent with fluorescent images taken under pressure. The PL center dominates the perylene group and the band edges are flat, indicating Frenkel exciton in the monolayer organic semiconductor under ambient conditions. With increasing pressure, the band edges become more dispersive, suggesting the exciton transform to Wannier-Mott exciton, which is commonly observed in inorganic semiconductors.
Related Concept Videos
π Electron Effects on Chemical Shift: Overview
π Electron Effects on Chemical Shift: Aromatic and Antiaromatic Compounds
Metal-Semiconductor Junctions
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The...
Biasing of Metal-Semiconductor Junctions
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
Semiconductors
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
Types of Semiconductors

